Beilstein J. Org. Chem.2021,17, 2932–2938, doi:10.3762/bjoc.17.202
-formyl amide products have unique properties and reactivity, but are difficult or impossible to access by traditional synthetic approaches.
Keywords: formylpeptide; nitroaryl compound; nitroso compound; olefin cleavage; photocleavage; Findings
The photochemistry of nitroaromatic functional groups has
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Graphical Abstract
Figure 1:
Uncaging of peptide backbone N–H bonds from Chan–Lam-type modification.